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Materiali molecolari basati su complessi inorganici

Salidu, Marco (2007) Materiali molecolari basati su complessi inorganici. [Doctoral Thesis]

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Abstract

Synthesis and characterization of molecular materials based on inorganic complexes. Recent news and perspectives about molecular materials. Syntheses of croconate (croc) and dithiocroconate (dtcr) ligands. New complexes based on croconate and dithiocroconate ligands, spectroscopic and structural properties of (TBA)2[Cu(dtcr)2], (TBA)[Au(dtcr)2], (TBA)3[Ga(croc)3]. New charge transfer salts based on dithiocroconate ligand, structural properties and electrical conductivity behavior of ET2[Ni(dtcr)2], TTF2[Ni(dtcr)2] e ET[Au(dtcr)2], initial spectroscopic characterization of ET/[Cu(dtcr)2] e TTF/[Cu(dtcr)2]. New complexes of Cr(III) with croconate ligand, spectroscopic and structural properties of [Cr(µ-C5O5)(µ-OH)(OH2)2]2[K5(C5O5)2.5]•7H2O e [Cr(µ-C5O5)(µ-OH)(OH2)2]2•6H2O, preliminary studies of magnetic properties and DFT calculations to clarify the bridge structure of the dimer [Cr(µ-C5O5)(µ-OH)(OH2)2]2•6H2O. Future perspectives on the use of these new complexes in the field of molecular materials.

Item Type:Doctoral Thesis
Date:02 February 2007
Tutor:Mercuri, Maria Laura
PhD classes:Ciclo 19 > Chimica
Coordinator:Ferino, Italo
Institution:Universita' degli Studi di Cagliari
Divisions:Dipartimenti (fino a dicembre 2011) > Dipartimento di Chimica inorganica analitica
Subjects:Area 03 - Scienze chimiche > CHIM/03 Chimica generale e inorganica
Uncontrolled Keywords:molecular materials, inorganic complexes, charge transfer, electrical conductivity
ID Code:180
Deposited On:06 Nov 2008 08:58

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